Zusammenfassung der Ressource
bonding
- ionic bonding
Anmerkungen:
- an ionic bond is an electrostatic force of attraction between oppositely charged ions caused by electron transfer.
- electrostatic attraction holds the
positive and negative ins together
very strongly.
- the formula for this compound tells you exactly what's in it.
- the positive charges balance the negative charges so the overall charge is zero.
- giant ionic lattices
- ionic crystals are giant lattices of ions, a
lattice is just a regular structure.
- the structures giant as its made up of the
same repeated unit over and over.
- behaviour of ionic compounds
- electrical conductivity
- ionic cmpounds only conduct when molten or dissolved
but not when solid. this is because theres no ions that are
free to carry the charge
- melting point
- ionic compounds have high melting point. the giant ionic lattices ar held together by strong
electrostatic forces and it requires a lot of enrgy to overcome these hence the higher
melting point.
- soluabiity
- ionic compounds tend to dissolve in water. water molecules are
polar. the water molecules pull the ions away from the lattice
causing it to dissolve
- covalent bonding
- molecules
- they're the smallest part of a compound
that can take part in chemical
reactions.theyre formed when two or more
atoms bond together. the atoms can be the
same (cl2) or different (CO)
- molecules are held
together by very
strong covalent
bonds
- single bonds
- in covalent bonding
two atoms share
electrons, so theyve
both got a 'full' outer
shell of electrons. both
the positie nuclei are
attracted
electrostatically to the
shared electrons.
- double or triple bonds
- double bond can be formed by the one carbon atom (c) which
can bond to two oxygens (O) each oxygen atom shares two pairs
of electrons with the carbon atom, so each molecule contains two
double bonds.
- triple bonds
- a triple bond occurs in
nitrogen (n2) the nitrogen
atom shares three pairs of
electrons so each nitrogen
contains one triple bond
- behaviour between simple covalent
compounds
- simple covalent compound
- they have STRONG bonds WITHIN molecules but
weak forces BETWEEN molecules. their physyical
properties such as conductiving electricity are
determined by the bonding in the compound
- electricial conductivity
- simple covalent compounds dont
conduct electricity because there are
no free ions to carry a charge
- melting points
- they have low melting points as the
weak forces between moleules are
easy to break
- soluability
- some of these compounds dissolve in
water depending on how polarised the
molecules are.
- giant covalent structures
- graphite
- carbon atoms are arranged in flat
hexangonal sheets. each carbon atom
is bonded to THREE OTHERS and the
fourth 'free' electron goes inbetween
the layers causing an delocalised
electron.
- what does graphites structure mean?
- the weak bonds between the layers
allow the sheets to slide over
eachother- it feels slippery and acts
as a lubricant
- the
delocalised
electrons
are free to
move
between
the sheets
and
therefore
can carry a
charge
- as the layers are quite far apart it ha a low density and
is used to make strong lightweight sport material
- graphites insoluable in any solvent
as the covalent bonds are to
difficult to break
- diamond
- diamonds made up of carbon
atoms, each carbons covalently
bonded to 4 others.
- the atoms arrange themselves in a tetrahedral shape.
- because of the strong covalent bonds...
- diamond has a very high melting point.
- diamonds extremely hard
- vibrations can travel easily
through the stiff lattice, so its a
god thermal conducltor.
- it cant conduct electricity as all the outer electrons are held in ionsied bond.
- and ike graohite it doent dissolve,
- dative covalent bonding
- a dative bond is a normal single covalent bond , however instead of
one atom donating each electron, both electrons are fro the same
atom
- you may need to idenitfy which atom in the question is the
'donor' and which is the 'reciever' . the donor has a LONE PAIR
OF ELECTRONS and the reciever has a VACANT ORBITAL.
- FOR EXAMPLE;
- the hydroxonium ion (H30+)
- first look at the reactants involves; in this case its H20 and H+
- a water molecule contains 2 hydrogens and 1 oxygen molecule
- oxygen has six electons in its outer shell and is filled with one electron each from the hydrogen atom
- only four of these 6 electrons take part in covalent bonding
- therefore the extra 2.. otherwise known as a 'LONE PAIR' are donated to the hydrogen ion. forming a DATIVE COVALENT/ CO-ORDINATE BOND
- METALLIC BONDING
- metal elements exist as giant metallic
lattice sturctures. the outerost shell of
electrons of a metal atom is delocalised ( the
electrons are free to move about the metal)
- this leaves a positive metal ion which are attracted to the delocalised negative
electrons. they form a lattice of closely packed positive ions in a sea of
delocalised electrons.
- BEHAVIOUR OF METALLIC COMPOUNDS
- melting point
- the number of delocalised electrons per
atom effects the melting point. the more
electrons the stronger the bonding will be
and the higher the melting point, for example
mg2+ has two delocalised electrons per atom
so its melting point will be higher than na+
- the size of the metal ion and the lattice
structure also effects melting point
- ability to be shaped
- as there are no specific bonds holding the atoms together the metals ions can
slide over eachother when the structures pulled, so the metals a malleable
and ductile
Anmerkungen:
- malleable means they can be hammered into shape and ductile means the can be drawn into thin wires
- conductivity
- as the delocalised electrons can pass kinetic energy to each other it
makes metas good thermal conductors and the electrons can carry a
current.
- soluability
- metals are insoluable except in liquid metals due to the
strength of the metallic bonds