Organic Chemistry (Aliphatic)

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Chemistry (Organic Chem) Mindmap am Organic Chemistry (Aliphatic), erstellt von Cindy Lam am 04/04/2013.
Cindy Lam
Mindmap von Cindy Lam, aktualisiert more than 1 year ago
Cindy Lam
Erstellt von Cindy Lam vor mehr als 11 Jahre
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Zusammenfassung der Ressource

Organic Chemistry (Aliphatic)
  1. Carboxylic Acid (RCOOH)
    1. Formation
      1. Oxidation of Aldehydes
        1. Hydrolysis of Esters, AC, nitriles, amides
        2. P.Prop
          1. H-bond → soluble in organic solvents and water
          2. RCOOH + PCL5 → RCOCl + POCl3 + HCl
            1. Formation of Acyl Chloride (RCOCl)
          3. Esters (R'COOR)
            1. Formation
              1. C.A + A: Reflux, Strong acid
                1. AC/AA + A: Reflux, Dry
                  1. AA less reactive → slower, less toxic, less exothermic
                2. C.Prop
                  1. Relatively unreactive
                  2. Hydrolysis break O bridge
                    1. Acidic: Reversible
                      1. Basic: 1D, Water soluble ionic salt formed, then react with HCl
                      2. Uses
                        1. Nice smell
                          1. Solvent
                            1. Plasticisers
                              1. Saponification - Alkaline Hydrolysis of triglycerol esters
                                1. Biodiesel
                              2. Amides (RCONH2)
                                1. Hydrolysis
                                  1. +H2O → RCOOH + NH3
                                    1. +HCl → RCOOH + NH4Cl
                                      1. +NaOH → RCOONa + NH3
                                      2. Reduce to primary amines
                                      3. Nitriles (RCN)
                                        1. Aldehydes (RCHO)
                                          1. Formation
                                            1. Oxi of primary Alcohols
                                              1. Reduction of CA
                                              2. Easily oxidised
                                              3. Ketones (R'COR)
                                                1. Oxi of secondary alcohols
                                                  1. Resistant to oxidation
                                                  2. Acyl Chlorides (RCOCl)
                                                    1. +Amines → N-substituted amides
                                                      1. +Ammonia → Amide
                                                        1. → Esters
                                                        2. Alcohol (ROH)
                                                          1. Identification Tests

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