The Acidic Environment

Beschreibung

year 12 Chemistry Mindmap am The Acidic Environment, erstellt von madi.stewardson am 28/03/2016.
madi.stewardson
Mindmap von madi.stewardson, aktualisiert more than 1 year ago
madi.stewardson
Erstellt von madi.stewardson vor fast 9 Jahre
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Zusammenfassung der Ressource

The Acidic Environment
  1. Indicators
    1. Bromothymol blue (yellow)6.2-7.6(blue) -Methyl orange (red)3.1-4.4(yellow) -phenolphthalein (colourless)8.3-10.0(pink)
    2. pH of oxides
      1. non-metal oxides- acidic
        1. metal oxides- basic
          1. amphoteric- can be both eg. H2O
          2. Le Chatelier’s Principle
            1. counteract any change in equilbrium
            2. oxide production
              1. sulfur oxides
                1. volcanoes-burning of fossil fuels - smelting metal ores
                2. nitrogen oxides
                  1. lightning- vechicles
                3. acid rain
                  1. pH <5 - SO or NO in H2O

                    Anmerkungen:

                    • SO2(g) + H2O(l) -&gt; H2SO3(aq) 2NO2(g) + H2O(l) -&gt; HNO3(aq) + HNO2(aq) 2H2SO3(aq) + O2(g) -&gt; 2H2SO4(aq) 2HNO2(aq) + O2(g) -&gt; 2HNO3(aq)
                    1. effects
                      1. kill aquatic ecosystem -leeches minerals needed for plants -erodes buildings
                    2. acids
                      1. weak
                        1. 1-99% ionised - CH3COOH (ethonoic acid - C6O7H8 (citric acid)
                        2. strong
                          1. 100% ionised -HCl - H2SO4
                        3. pH = -log10[H+]
                          1. %ionisation = [H+] divide [acid] x 100
                            1. History
                              1. Lavosier- acid oxygen
                                1. Davy- replaceable hydrogen
                                  1. Arrhenius- H+ and OH-
                                    1. Bronsted and Lowry- acid proton donor base proton accepter
                                    2. Conjugate acid/base
                                      1. molecules related by the loss or gain of a proton eg. H20 (acid) and H30+ (conjugate base(accepted))
                                      2. neutralisation reactions
                                        1. salt based on stronger acid/base -strong+strong=neutral salt + H2O
                                        2. Buffer
                                          1. weak acid and conjugate base eg. HCO3- and CO3 2-
                                            1. used in blood, minimises pH change
                                            2. Titration
                                              1. reacting a solution of unknown concentration with a standard
                                                1. method

                                                  Anmerkungen:

                                                  • (1) Choose indicator which has an end point suitable to equivalence point (2) Rinse glassware with distilled water, and then with the acid/base (3) Wash conical flask with distilled water (4) Fill 25mL pipette with aliquot of standard solution in volumetric flask (5) Add 3 drops of indicator to the flask (6) Fill burette with titrant, using dropper to add the final volumes (7) Assemble retort stand and equipment appropriately (8) Titrate with the left hand and swirl with right. Repeat 3 times for accuracy.
                                                2. acids in food
                                                  1. -flavour enhancers -preservative -anti-oxidant
                                                  2. carbon dioxide
                                                    1. high pressure- CO2 gas dissolves
                                                      1. temperature - dissolving of gas is exothermic
                                                        1. Acidity- acid would create more CO2 gas
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