Group 7: The Halogens

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Group 7: The Halogens
  1. Physical Properties
    1. A family of non-metalic elements
      1. All are very reactive, and are very strong oxidising agents
        1. Governed by the fact that they have 7 electrons in there outest shell
          1. Most common oxidation No. for halogens is -1, but others do exist
          2. The further down the group the darker and less volatile the elements become, also less reactive
            1. Chlorine(g) is green/yellow in colour, Bromine(l) is brown and Iodine(s) shiney grew/black
            2. The solubility of halogens in water decresded down the group
              1. Halogens are non-polar, dissolve better in hydrocarbonsolvents
                1. But Chlorine id readily reacted with water
                  1. Cl(2) + H2O = HCL + HClO
              2. Oxidation Reactions
                1. Metals
                  1. Halogens better with more elctroposative elements like metals
                    1. This means that when they do react they remove some or all of a metals outer elctrons
                      1. This is especialy true for group 1 and 2 elements
                        1. Mg + Cl(2) = MgCl(2)
                    2. Non-metals
                      1. Halogens reacting with non-metals usually react a nobal gas configuration of e-
                        1. An example of a non-metal halognes react with is phosphorus
                          1. Chlorine forms Phosphorus(iii) chloride
                            1. 2P + 3Cl(2) = 2PCl(3)
                              1. With an excess of chlorine it will form Phosphorus(v) chloride
                        2. Iron(ii) chloride
                          1. reaction ocurrs when a halogen is added to the reactant in solution
                            1. 2FeCl(2)+Cl(2)= 2FeCl(3)
                            2. The halogen oxidises the green Iron(ii) to brown Iron(iii)
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