When the ligands bond with the transition metal ion, there is ❌ between the electrons in the ligands and the electrons in the d orbitals of the ❌. That raises the energy of the d orbitals.
However, because of the way the d orbitals are arranged ❌, it doesn't raise all their energies by the same amount. Instead, it splits them into ❌, one group of 2 orbitals with a slightly ❌ energy level than the other 3.
The size of the energy gap between them varies with the nature of the transition metal ion, its ❌ (whether it is 3+ or 2+, for example), and the nature of the ❌.
When ❌ is passed through a ❌ of this ion, some of the energy in the light is used to ❌ an electron from the lower set of orbitals into a space in the upper set. The amount of energy absorbed in order to promote this electron corresponds to a ❌ of the visible light. We therefore see a combination of the other colours in the spectrum, which often shows as the ❌ colour of the one absorbed.
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oxidation state
oxidation state
complementary
complementary