Zusammenfassung der Ressource
Frage 1
Frage
How do you identify a carbonyl compound?
Antworten
-
Add Tollens' reagent
-
Add Biuret reagent
-
Add 2,4-DNPH
-
Add carboxylic acid
Frage 2
Frage
What is Brady's reagent?
Antworten
-
A mixture of H2SO4 and benzene + 2,4-DNPH
-
A mixture of HCl and ethanol + 2,4-DNPH
-
A mixture of NaOH and methanol + 2,4-DNPH
-
A mixture of H2SO4 and methanol + 2,4-DNPH
Frage 3
Frage
What's formed when 2,4-DNPH is added to an aldehyde/ketone?
Frage 4
Frage
What does the 2,4-DNPH derivative confirm?
Antworten
-
The presence of C=O
-
The presence of COOH
-
The presence of OH
-
The presence of COO
Frage 5
Frage
What happens when 2,4-DNPH added to carboxylic acid/ester?
Frage 6
Frage
What is Tollen's reagent?
Antworten
-
A weak oxidising agent
-
A weak reducing agent
-
A strong oxidising agent
-
A strong reducing agent
Frage 7
Frage
What happens to aldehydes when Tollens' reagent is added to it?
Frage 8
Frage
What observation do you see when Tollen's reagent is added to an aldehyde?
Antworten
-
Brown precipitate
-
Silver mirror
-
No observation
-
Brick red precipitate
Frage 9
Frage
Why is a silver mirror formed?
Antworten
-
Al ions oxidised to Al metal
-
Silver ions reduced to silver metal
-
Silver ions oxidised to silver metal
-
Al ions reduced to Al metal
Frage 10
Frage
What is the equation for the silver mirror being formed?
Antworten
-
Ag-(aq) + e+ ---> Ag(s)
-
Ag+(aq) ---> Ag(s) + e-
-
Ag+(s) + e- ---> Ag(aq)
-
Ag+(aq) + e- ---> Ag(s)
Frage 11
Frage
What observation do you see when Tollen's added to ketone?
Frage 12
Frage
What's the reason for no observation?
Frage 13
Frage
What's the oxidising species in Tollens' reagent?
Antworten
-
Ag(aq)
-
Br+(aq)
-
Ag(s)
-
Ag+(aq)
Frage 14
Frage
What conditions are required for these reactions?
Antworten
-
Warm
-
Reflux
-
conc H2SO4
-
Alkaline
Frage 15
Frage
Filter and [blank_start]recrystallise[blank_end] product. Measure [blank_start]melting point[blank_end] of purified product which is very [blank_start]high[blank_end]. Compare the melting point to a [blank_start]database[blank_end] or [blank_start]data table[blank_end] to identify the unknown product and therefore the [blank_start]original[blank_end] carbonyl compound.
Antworten
-
recrystallise
-
melting point
-
high
-
database
-
data table
-
original
Frage 16
Frage
Why does the yellow/orange solid have to be recrystallised?
Antworten
-
Because it needs to be crystallised again
-
Because its slightly impure
-
Because it's fun
-
Because it needs to be more solid
Frage 17
Frage
Why can't boiling points be used to distinguish between aldehydes and ketones?