Chemical tests for carbonyl compounds

Beschreibung

A-Level Chemistry (F324: Rings, Acids & Amines) Quiz am Chemical tests for carbonyl compounds, erstellt von anndjan21 am 14/03/2016.
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Quiz von anndjan21, aktualisiert more than 1 year ago
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Zusammenfassung der Ressource

Frage 1

Frage
How do you identify a carbonyl compound?
Antworten
  • Add Tollens' reagent
  • Add Biuret reagent
  • Add 2,4-DNPH
  • Add carboxylic acid

Frage 2

Frage
What is Brady's reagent?
Antworten
  • A mixture of H2SO4 and benzene + 2,4-DNPH
  • A mixture of HCl and ethanol + 2,4-DNPH
  • A mixture of NaOH and methanol + 2,4-DNPH
  • A mixture of H2SO4 and methanol + 2,4-DNPH

Frage 3

Frage
What's formed when 2,4-DNPH is added to an aldehyde/ketone?
Antworten
  • A blue solid
  • An orange/yellow precipiate
  • An orange/yellow solution
  • A green precipitate

Frage 4

Frage
What does the 2,4-DNPH derivative confirm?
Antworten
  • The presence of C=O
  • The presence of COOH
  • The presence of OH
  • The presence of COO

Frage 5

Frage
What happens when 2,4-DNPH added to carboxylic acid/ester?
Antworten
  • An orange/yellow precipitate formed
  • An orange to green colour change
  • A solid disappears
  • No precipitate formed

Frage 6

Frage
What is Tollen's reagent?
Antworten
  • A weak oxidising agent
  • A weak reducing agent
  • A strong oxidising agent
  • A strong reducing agent

Frage 7

Frage
What happens to aldehydes when Tollens' reagent is added to it?
Antworten
  • Oxidised to ketones
  • Reduced to carboxylic acids
  • Oxidised to carboxylic acids
  • Reduced to alcohols

Frage 8

Frage
What observation do you see when Tollen's reagent is added to an aldehyde?
Antworten
  • Brown precipitate
  • Silver mirror
  • No observation
  • Brick red precipitate

Frage 9

Frage
Why is a silver mirror formed?
Antworten
  • Al ions oxidised to Al metal
  • Silver ions reduced to silver metal
  • Silver ions oxidised to silver metal
  • Al ions reduced to Al metal

Frage 10

Frage
What is the equation for the silver mirror being formed?
Antworten
  • Ag-(aq) + e+ ---> Ag(s)
  • Ag+(aq) ---> Ag(s) + e-
  • Ag+(s) + e- ---> Ag(aq)
  • Ag+(aq) + e- ---> Ag(s)

Frage 11

Frage
What observation do you see when Tollen's added to ketone?
Antworten
  • No observation
  • Silver mirror
  • Deep blue solution
  • Orange to green colour change

Frage 12

Frage
What's the reason for no observation?
Antworten
  • The reaction is too slow
  • Ketones are not reduced by Tollens' reagent
  • Ketones are not oxidised by Tollens' reagent
  • Ketones are just dead

Frage 13

Frage
What's the oxidising species in Tollens' reagent?
Antworten
  • Ag(aq)
  • Br+(aq)
  • Ag(s)
  • Ag+(aq)

Frage 14

Frage
What conditions are required for these reactions?
Antworten
  • Warm
  • Reflux
  • conc H2SO4
  • Alkaline

Frage 15

Frage
Filter and [blank_start]recrystallise[blank_end] product. Measure [blank_start]melting point[blank_end] of purified product which is very [blank_start]high[blank_end]. Compare the melting point to a [blank_start]database[blank_end] or [blank_start]data table[blank_end] to identify the unknown product and therefore the [blank_start]original[blank_end] carbonyl compound.
Antworten
  • recrystallise
  • melting point
  • high
  • database
  • data table
  • original

Frage 16

Frage
Why does the yellow/orange solid have to be recrystallised?
Antworten
  • Because it needs to be crystallised again
  • Because its slightly impure
  • Because it's fun
  • Because it needs to be more solid

Frage 17

Frage
Why can't boiling points be used to distinguish between aldehydes and ketones?
Antworten
  • It's not possible to know all of the boiling points for every single one
  • It will all boil away
  • Some are very close together/similar
  • It's not accurate enough
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