enthalpy

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enthalpy notes
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Conservation of Energy 1st Law of Thermodynamics Energy can neither be created nor destroyed - it can only change form The total Energy of the universe is constant = 1st Law of Thermodynamics
System System = part of universe under study (e.g. - chemicals in a flask)
Surroundings Surroundings = the rest of the universe (or as much as needed (e.g. - the flask)
Universe Universe = System + Surrounds
Internal Energy Internal Energy depends on: Temperature Type of material (mass and particles) Amount of material (number of particles)
Calculating Thermodynamic Changes Energy change of a final system = ΔE = E final - E initial
ΔE positive : internal energy increases
ΔE negative : internal energy decreases
Heat Capacity Heat capacity = E required to raise the T(temperature) of an object by 1°C Specific Heat Capacity = E required to heat 1 gram of substance by 1°C Molar Heat Capacity = E required to heat 1 mole of substance by 1°C
Specific Heat Energy required to change Temp of an object is: Heat required = mass x specific heat x ΔTq = m c ΔT or… Heat required = moles x molar heat capacity x ΔT q = n cm ΔT
When heat is ADDED to a system q (heat) is positive the change is endothermic temperature decreases (liquid water boils to become gaseous water)
When heat is REMOVED from a system q (heat) is negative the change is exothermic temperature increases (gaseous water condenses to become liquid water)
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