proton: mass 1,charge +1 ,location in atom.electron:mass 0, charge -1, location in
the nucleus can be described as two
different parts the atomic number z
and the mass number A. the atomic
number is number of protons. it is
numerically the charge on the
nucleus.mass number =atomic
number +number of neutrons.
isotopes are the same element with different mass numbers.differences
in mass are caused by the difference in neutrons
most elements exist as isoptopes, the relative atomic mass is an average of relative isotopic
masses taking in count their abundances a techinque called mass spectrometry
mass spectrometry
mass spec measures the atomic or molecular mass of different particles in a sample
and the relative abundance of different isotopes in the element
the atoms are ionised to positively charged cations. these ions are separated according to their mass m to
change z ratios. m/z. seperate ions are detected along with their relative abundance
nuclear fission
two light nuclei fuse together forming a single
heavier nucleus of a new element releasing
enormous amounts of energy. for two nuclei to fuse
they must be very close together.
on normal temperatures on earth this will not happen
as the positive nuclei repel so strongly the fusion can not
happen
in very high temperatures like stars the nuclei are moving
quickly and collide with so much energy the repulsion is
overcome
spectroscopy
glowing stars emit across the board of
frequencies. the sun mainly emits visible
light but other hotter stars emit mainly
ultraviolet light
outside the star's surface is a region called the photosphere contains
things like the ions and atoms these are the molecules that absorb some
of emitted light so the frequencies from the stars are missing. the absorption lines are black lines.
emission . when atoms are raised from their ground state to higher energy states
called excited states.the particles can lose their energy by emitting electromagnetic
radiation.
Bohr's theory
the theory that light
is a wave and a
particle none of them
explains all the
properties of light
particle theory- this shows that light is a stream of tiny packets of photons.the
energy of the photons is related to the position in the em scale.photons energy is 3 x10^-19
energy of a photon(E) = plancks constant x frequency
plancks constant = 6.63 x 10^-34
the wave theory -a wave of light travels the distance between two points in a certain time, it
does not matter what light and the time is always the same. the speed waves moves is at the
speed of c which is light and is 3.00 x 10^8 when traveling in a vacuum.
speed of c =wavelength(M) x frequency(s-1)
when an atom is excited it will raise an energy level
later they will drop back down emitting the extra
energy
when light light passes through a cool sample of a gaseous
sample black lines appear in the otherwise continuous
absorption spectrum. each element has it's own line pattern and
can be used to identify if an element is present in a mixture
however Bohr's can only
explain absorption and
emission spectrum and the
electronic structure of
atoms
main points:the electron in the
hydrogen atom exists only certain
definite energy or electron levels, a
photon of light is emitted or absorbed
when the electrons changes from one
energy level to another,the energy of a
photon is equal to the difference
between two levels,since E=hv it follows
that the frequency of emitted or
absorbed light is related to delta E by
delta E=hv
sub shells: s shell is
containing two
electrons ,p has 6
electrons ,d has 10
electrons and, f is 14
electrons
s has one orbital
p has three
d has five
f has seven
each orbital can contain two electrons, electrons in a atom spin, electrons can
only occupy the same orbital if they have opposite spins
the box represents the atomic orbital and the arrows represent the electrons four
pieces of information are needed when describing an electron
the electron shell it is in ,it's sub shell,it's orbital within the shell,it's spin
the electron configuration of an atom is the arrangement of shells and orbitals. the orbitals are filled in order of increasing
energy when there is more than one orbital with the same energy these first orbitals are first occupied singly by electrons
this keeps the electrons as far apart as possible
periodic table
Mendeleev arranged the periodic table in order of increasing
mass and elements with similar properties were in the same
vertical group, however his values were incorrect becayse
they had not discovered isoptopes yet
he left gaps in the table for elements that has not been discovered
yet. his prediction for the gaps in the table was accurate with the
newly discovered element at the time gernamium in 1886
periodicity
in the new table it seem it the same going up in atomic mass but
it is not it's going up in the number of protons in the nucleus with
the exception of hydrogen the periodic table can be put into the
orbital blocks
vertical columns are called groups
horizontal columns are called periods
there are trends in the properties as you go down the
group but properties vary in a fairly regular way as you
move across a period from left to right,
the most obvious one is the zig-zag line across the p block the elements to
the left of it have the properties of metals and element to the right the
properties of non metals