Created by joannalivesey
over 10 years ago
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alkane -> halogenoalkane
alkene -> halogenoalkane
alkene -> bromoalcohol
alkene -> dihalogenoalkane
alkene -> alkane
alkene -> alcohol
alkene-> addition polymer
homolytic fission of halogenoalkanes
heterolytic fission of halogenoalkanes
halogenoalkane -> alcohol
halogenoalkane -> amine
halogenoalkane -> nitrile (R-CN) + halide ion
primary alcohol -> bromoalkane
primary alcohol -> chloroalkane
primary alcohol -> alkene
primary alcohol -> aldehyde. (oxidation)
primary alcohol -> carboxylic acid. (oxidation)
secondary alcohol -> ketone. (oxidation)
aldehyde -> primary alcohol.
(reduction)
ketone -> secondary alcohol. (reduction)
aldehyde -> cyanohydrin
ketone -> cyanohydrin
aldehyde -> carboxylic acid
carboxylic acid -> ester
phenol -> ester
ester hydrolysis
alkylation of a primary amine
making primary amides (acylation)
making secondary amides (acylation)
amide hydrolysis
Benzene -> cyclohexane
nitrobenzene -> phenylamine
phenyl amine -> benzenediazonium ion (diazotisation)
diazonium ion -> azo compound
benzene
nitration
benzene sulfonation
benzene chlorination
benzene
Bromination
benzene
alkylation
benzene
acylation
advantages of friedel-craft
tests:
alcohol + NaOH
tests:
phenol + NaOH
tests:
carboxylic acid + NaOH
tests:
alcohol + carbonate
tests:
phenol + carbonate
tests:
carboxylic acid + carbonate
test for phenol
[Fe(H2O)6]2+
[Fe(H2O)6]3+
Fe(OH)2(s)
Fe(OH)3(s)
[Cu(H2O)6]2+
[Cu(NH3)4(H2O)2]2+
[CuCl4]2-
Cu(OH)2(s)
N2O
NO2
NO
shape of N2
shape of ammonia
shape of ammonium ion
shape of nitrate (III) ion
shape of nitrate (V) ion
test for aldehyde
carboxylic acid -> aldehyde
carboxylic acid -> acyl chloride
nitrile -> carboxylic acid
coupling reaction