Basic Concepts and Hydrocarbons

Descripción

Undergraduate (Basic Concepts and Hydrocarbons) Chemistry - Part 2 Fichas sobre Basic Concepts and Hydrocarbons, creado por siobhan.quirk el 24/05/2013.
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Resumen del Recurso

Pregunta Respuesta
pi-bond reactive part of a double bond formed above and below the plane of the bonded atoms by sideways overlap of p-orbitals
Electrophilic addition a type of addition reaction in which an electrophile is attracted to an electron-rich centre or atom, where it accepts a pair of electrons to form a new covalent bond
Carbocation an organic ion in which a carbon atom has a positive charge
Curly arrow a symbol used in eaction mechanisms to show the movement of an electron pair in the formation or breaking of a covalent bond
Polymer long molecular chain built up from monomer units
Monomer small molecule that combines with many other monomers to form a polymer
Addition Polymerisation the process in which unsaturated alkene molecules add on to a growing polymer chain one at a time, to form a very long saturated molecular chain
Addition polymer a very long molecular chain, formed by repeated addition reactions of many unsaturated alkene molecules
Repeat unit specific arrangement of atom that occurs in the structure over and over agin. Repeat units are included in brackets, outside of which is the symbol n
Biodegradable material a material that is broken down naturally in the environment by living organisms
Radical substitution a type of substitution reaction in which a radical replaces a different atom or group of atoms
Mechanism a sequence of steps showing the path taken by electrons in a reaction
Initiation the first step in a radical substitution in which the free radicals are generted by ultraviolet radiation
Propagation two repeated steps in radical substitution that build up the products in a chain reaction
Termination the step at the end of a radical substitution when two radicals combine to form a molecule
Cracking the breaking down of long-chained saturated hydrocarbons to form a mixture of shorter-chained alkanes and alkenes
Catalyst a substance that increases the rate of a chemical reaction without being used up in the process
Fractional Distillation the separation of the compounds in a liquid mixture into fractions which differ in boiling point by means of distillation, typically using a fractionating column
Homolytic fission the breaking of a covalent bond, with one of the bonded electrons going to each atom forming two radicals
Radical species with an unpaired electron
Heterolytic fission breaking of a covalent bond with both of the bonded electrons going to one of the atoms, forming a cation and an anion
Nucleophile an atom that is attracted to an electron-deficent centre or atom, where it donates a pair of electrons to form a new covalent bond
Electrophile an atom that is attracted to an electron-rich centre where it accepts a pair of electrons to form a new covalent bond
Addition reaction a reactant is added to an unsaturated molecule to make a saturated molecule
Subsitution reaction where an atom is replaced with a different atom
Elimination reaction the removal of a molecule from a saturated molecule to form an unsaturated molecule
Structural isomers molecules with the same molecular formula but with different structural arrangments of atoms
Stereoisomers compounds with the same structural formula, but with a different arrangment of atoms in space
E/Z isomerism a type of stereoisomerism in which different groups attached to each carbon of a C=C double bond may be arranged differently in space because of the restricted rotatio of the C=C bond
cis-trans isomerism type of E/Z isomerism where a non-hydrogen group and hydrogen on each C of a C=C bond. the cis has the H atoms on the carbon on the same side. Trans has H on each C on different sides
Structural formula shows the minimal detail for the arrangement of atoms in a molecule
Skeletal formula simplified organic formula, with hydrogen atoms removed from alkyl chains, leaving just a carbon skeleton and associated functional groups
Displayed formula shows the relative positioninf of all the atoms in a molecule and the bonds between them
General formula simplest algebraic formula of a member of a homologous series
Nomenclature system of naming compounds
Alkyl Group an alkan with a hydrogen atom removed e.g. CH3
Hydrocarbon organic compounds that contain carbon and hydrogen only
Saturated hydrocarbon is a hydrocarbon with single bonds only
Unsaturated hydrocarbon a hydrocarbon containing carbon-to-carbon multiple bonds
Aliphatic hydrocarbon a hydrocarbon with carbon atoms joined together in a straight or brached chain
Alicyclic hydrocarbons a hydrocarbon with carbon atoms joined together in a ring structure
Functioning Group part of the organic molecule responsible for the chemical reactions
Homologous series series of organic compounds with the same functional group but with each successive member differing by CH2
Alkanes the homologous series with the general formula CnH2n+2
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