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Orgo 2 Exam 2

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umich orgo 2 exam 2
Katherine Siller
Fichas por Katherine Siller, actualizado hace más de 1 año
Katherine Siller
Creado por Katherine Siller hace más de 6 años
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Pregunta Respuesta
carboxylic acid + SOCl2 or PCl3
Image: Screen Shot 2018 03 12 At 3.37.03 Pm (binary/octet-stream)
carboxylic acid + carboxylic acid
Image: Screen Shot 2018 03 12 At 3.38.19 Pm (binary/octet-stream)
carboxylic acid + H2SO4, CH3OH
Image: Screen Shot 2018 03 12 At 3.44.09 Pm (binary/octet-stream)
acyl transfer: anionic nuc 2 steps tetrahedral intermediate
acyl transfer: neutral nuc + weak base 3 steps zwitterion tetrahedral intermediate
acyl transfer: neutral nuc + strong acid 6 steps tetrahedral intermediate
primary alcohol + CrO3 + H2SO4 + H2O
Image: Screen Shot 2018 03 12 At 3.50.47 Pm (binary/octet-stream)
aldehyde + CrO3 + H2SO4 + H2
Image: Screen Shot 2018 03 12 At 3.50.47 Pm (binary/octet-stream)
+ H2SO4 + H2O
Image: Screen Shot 2018 03 12 At 3.51.54 Pm (binary/octet-stream)
Image: Screen Shot 2018 03 12 At 3.51.58 Pm (binary/octet-stream)
+ NaOH + H2O
Image: Screen Shot 2018 03 12 At 3.51.54 Pm (binary/octet-stream)
Image: Screen Shot 2018 03 12 At 3.52.10 Pm (binary/octet-stream)
Ph-MgBr + CO2 + H3O(+)
Image: Screen Shot 2018 03 12 At 3.54.49 Pm (binary/octet-stream)
+ TsOH -----> CH3OH
Image: Screen Shot 2018 03 12 At 3.50.47 Pm (binary/octet-stream)
+ H2O
Image: Screen Shot 2018 03 12 At 3.51.54 Pm (binary/octet-stream)
+ TsOH
Image: Screen Shot 2018 03 12 At 3.58.35 Pm (binary/octet-stream)
Image: Screen Shot 2018 03 12 At 3.58.41 Pm (binary/octet-stream)
+ LiAlH4
Image: Screen Shot 2018 03 12 At 3.54.49 Pm (binary/octet-stream)
aldehyde, then won't stop (can be protonated to primary alcohol)
Image: Screen Shot 2018 03 12 At 4.00.12 Pm (binary/octet-stream)
carboxylic acid won't reaction with NaBH4 only LiAlH4
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