Princles of chemistry

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Edexcel IGCSE
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Describe the particles in a solid. (e.g. spacing, arrangement, movement and forces) Close together and touching one another Regular, repeating pattern Vibrate about a fixed position, but do not move apart The force between particles in stronger than in a liquid or gas
Describe the particles in a liquid. (e.g. spacing, arrangement, movement and forces) Close together and touching one another Irregular arrangement Move around and slide past one another Forces are not as strong as in a solid, but stronger than in a gas
Describe the particles in a gas. (e.g. spacing, arrangement, movement and forces) Spaced far apart An irregular arrangement Move freely and constantly collide with one another Non-existent forces between particles
What is the change called when: * a solid changes to a liquid? *a liquid changes to a solid? *a liquid changes to a gas? *a gas changes to a liquid? *a solid changes to a gas? * solid-liquid = Melting *liquid-solid = Freezing *liquid - gas = Boiling/evaporating *gas - liquid = Condensing *solid - gas = Subliming
Explain, in terms of particles, the change between a liquid to a gas. The particles gain kinetic energy and move further apart. Eventually the forces of attraction between the particles are completely broken and they are able to escape from the liquid.
Explain, in terms of particles, the change between a liquid to a solid. The particles lose kinetic energy and this allows the forces of attraction between the particles to hold them together. The particles arrange themselves into a regular pattern are no longer able to slide past one another.
Give two pieces of evidence to support the particle theory. *Dilution of coloured solutions - Potassium Manganate crystals are dissolved in water a purple solution is formed- large number of particles in small amount of solid *Diffusion- Bromine from one flask to another- particles in gas easily mix together
What is an atom? Smallest particle of an element that can take place in a chemical reaction
What is an element? A substance made up of atoms which all contain the same number of protons.
What is a compound? A substance made up of two or more elements chemically combined together.
What is a mixture? A combination of two or more substances that are not chemically joined together.
What is a molecule? The smallest particle that can have a separate, independent existence.
When should you carry out filtration? To separate an undissolved solid from a mixture of the solid and a liquid/solution (e.g. sand from a mixture of sand and water)
When should you carry out evaporation? To separate a dissolved solid from a solution, when the solid has similar solubilities in both hot and cold solvent (e.g. sodium chloride from a solution of sodium chloride in water)
When should you carry out crystallisation? To separate a dissolved solid from a solution, when the solid is much more soluble in hot solvent than in cold (e.g. copper sulphate from a solution of copper sulphate in water)
When should you carry out simple distillation? To separate a liquid from a solution (e.g. water from a solution of sodium chloride in water)
When should you carry out fractional distillation? To separate two or more liquids that are miscible with one another (e.g. ethanol and water from a mixture of the two)
What are miscible liquids? Liquids which will mix together.
When should you carry out paper chromatography? To separate substances that have different solubilities in a given solvent (e.g. different coloured inks that have been mixed together to make black ink)
What is thermal decomposition? Breaking down by using heat
What is electrolysis? The decomposition of a substance by passing an electric current through it
What is an atom made up of? Proton Electron Neutron
Relative charge, relative mass and position of the three sub-atomic particles Neutron- charge 0, mass 1, nucleus Proton- charge 1, mass 1, nucleus Electron- charge -1, mass 0, electron shells
What is the atomic number? Number of protons in the nucleus of an atom of an element
What is the mass number? Number of protons + number of neutrons in the nucleus of an atom of an element
What is the top number showed by the element in the periodic table? Mass number
What are isotopes? Atoms that have the same atomic number (same number of protons) but different mass numbers (different number of neutrons)
Electrons exist ............. the nucleus of atoms in different ................ ....................... called ................. .................... . There are several .................. ....................... . around energy levels electron shells electron shells
What is Ar? Relative atomic mass (Mean mass of all the isotopes of a particular element)
What is Mr? Relative formula mass- The sum of all the relative atomic masses of all the atoms present in the formula of a substance.
What is a mole? 1 mole is the amount of substance that contains 6 x 10^23 particles (atoms, molecules or formulae) of the substance.
How do you calculate the mass of 1 mole? the relative atomic mass (Ar) expressed in grams
How do you calculate the mass of a substance (in grams) from the amount (number of moles)? amount of moles x Mr
How do you calculate the amount in moles from the mass of the substance? Mass of substance (grams) / Mr
What is the molar volume? One mole of any gas has a volume of 24dm^3 at room temperature and pressure.
How to work out the volume of gas (in dm^3 and cm^3) from the amount of gas? Volume in dm^3 = amount x 24 Volume in cm^3 = amount x 24 000
How to work out the amount of gas (in moles) from the volume of gas in a) dm^3 b) cm^3 a) volume (in dm^3) / 24 b) volume (in cm^3) /24 000
What is the empirical formula? The simplist whole number ratio
How do you work out the empirical formula? (e.g. percentage composition: aluminium = 52.94 %; oxygen = 47.06 % empirical formula of Aluminium Oxide?) Divide by Ar (Al= 52.94 / 27=1.96 O= 47.06 / 16=2.94) Divide by smallest to find ratio (Al =1.96/1.96 = 1 O=2.94 / 1.96 = 1.5) 2:3 Al2O3
What is the molecular formula? The exact number of atoms
How do you work out the amount of dissolved substance (in moles) using the concentration? [volume of solution (in cm^3) x concentration of solution (in mol/dm^3)] / 1000
What is the theoretical yield? The maximum amount of a product that could be formed from a given amount of a reactant
How do you calculate a percentage yield? (Yield obtained / theoretical yield) / 100
What is an ion? How are ions formed? An electrically charged atom or group of atoms By the loss or gain of electrons
What things make ionic compounds? What is an ionic bond? atoms of metals and atoms of non-metals Electrostatic force of attraction between oppositely charged ions (e.g. transferred electrons)
There are no ..................... in ionic compounds. Molecules
Why do ionic compounds have a high melting and boiling point? Electrostatic forces are strong and there is many of them to break in an ionic crystal. Therefore a large amount of energy is required to overcome the forces.
When are covalent bonds formed? What is a covalent bond? Between atoms of non-metallic elements The force of attraction between the nuclei of two atoms and a pair of electrons shared between them
Simple molecular substance have .......... melting and boiling points because the forces of attraction between the molecules are ....... and therefore ........... energy is required to overcome them. low weak little
Give 2 examples of giant covalent structures made from carbon. Describe the bonding in them. Describe the forces in them. Diamond - Each carbon atom forms four single covalent bonds. 3D structure formed. Covalent bonds are strong. No weak forces in the structure. Graphite - Each carbon atoms forms 3 single covalent bonds. Layered structure formed. Covalent bonds- strong. Forces of attraction between layers -weak
Describe the uses and properties of diamond. Very high melting point Very hard and abrasive Does not conduct electricity Cutting tools Jewellery
Describe the properties and uses of graphite. Very high melting point. Soft and slippery. Conducts electricity. Lubricant Electrodes for electrolysis
Describe the structure of metals. Properties of metals Giant, 3D lattice structure of positive ions in a sea of delocalised valence electrons High melting and boiling points Good conductors of electricity Malleable and ductile
What are the conditions of electrolysis? What is the electrolyte? Ionic compounds when molten or an aqueous solution Substance being electrolysed
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