17782927
Descripción
Fichas por John Rivada, actualizado hace más de 1 año
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Creado por John Rivada
hace más de 5 años
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| Pregunta | Respuesta |
| Properties for kinetic product | -Forms faster -Rx usually short -Low temperature -Reversible under thermodynamic conditions |
| Properties for thermodynamic product | -Forms more slowly but more stable -Rx is long -High temperature -Irreversible |
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1b (binary/octet-stream)
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1a (binary/octet-stream)
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1c (binary/octet-stream)
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1a (binary/octet-stream)
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Mechanism?
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1a (binary/octet-stream)
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2a (binary/octet-stream)
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3b (binary/octet-stream)
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3a (binary/octet-stream)
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3c (binary/octet-stream)
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3a (binary/octet-stream)
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4b (binary/octet-stream)
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4a (binary/octet-stream)
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4c (binary/octet-stream)
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4a (binary/octet-stream)
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Mechanism?
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4a (binary/octet-stream)
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4d (binary/octet-stream)
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5b (binary/octet-stream)
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5a (binary/octet-stream)
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5c (binary/octet-stream)
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5a (binary/octet-stream)
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6b (binary/octet-stream)
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6a (binary/octet-stream)
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6c (binary/octet-stream)
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6a (binary/octet-stream)
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| How do you protect the amine group of an amino acid? | Cbz Benzyl chloroformate |
| How do you protect the amine group of an amino acid? | Boc (t-BuOCO) Deprotect with H+ and H2O |
| How do you protect the amine group of an amino acid? | FMoc-Cl, base Deprotect with amine base (e.g. pyridine) |
| How to make t-butyl ester | ** |
| How do you protect the carboxylic acid group of an amino acid? | ROH, H+ Deprotect with -OH (LiOH, NaOH) |
| How do you protect the carboxylic acid group of an amino acid? | isobutene, H+ Deprotect with strong acid |
| How do you protect the carboxylic acid group of an amino acid? | PHCH2OH and H+ or PhCH2Br and base Deprotect with H2 + cat. Pd/C or -OH |
| Slide 27 | ** |
| Slide 29 | ** |
| Slide 30 | ** |
| Solid phase peptide synthesis | 88 |
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