Chem 5 - Reactions of Metals in Aqueous Solution

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Chem 5 - Reactions of Metals in Aqueous Solution
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Aqueous Ion Iron(II) [Fe(H₂O)₆]²⁺ (aq) green solution
Action of NaOH Iron(II) Fe(H₂O)₄(OH)₂ (s) green ppt goes brown on standing in air
Action of an excess of NaOH (aq) Iron(II) No further change
Action of NH₃ (aq) Iron(II) Fe(H₂O)₄(OH)₂ (s) green ppt goes brown on standing in air
Action of an excess of NH₃ (aq) Iron(II) No further change
Action of Na₂CO₃ (aq) Iron(II) FeCO₃ (s) green ppt
Aqueous Ion Copper(II) [Cu(H₂O)₆]²⁺ (aq) blue solution
Action of NaOH Copper(II) Cu(H₂O)₄(OH)₂ (s) blue ppt
Action of an excess of NaOH (aq) Copper(II) No further change
Action of NH₃ (aq) Copper(II) Cu(H₂O)₄(OH)₂ (s) blue ppt
Action of an excess of NH₃ (aq) Copper(II) [Cu(H₂O)₂(NH₃)₄]²⁺ (aq) deep blue solution
Action of Na₂CO₃ (aq) Copper(II) CuCO₃ (s) blue-green ppt
Action of HCl (aq) Copper(II) [CuCl₄]²⁻ (aq) yellow solution (may look green)
Aqueous Ion Iron(III) [Fe(H₂O)₆]³⁺ (aq) purple solution (may look yellow-brown due to some [Fe(H₂O)₅(OH)]²⁺)
Action of NaOH Iron(III) Fe(H₂O)₃(OH)₃ (s) brown ppt (may look orange-brown)
Action of an excess of NaOH (aq) Iron(III) No further change
Action of NH₃ (aq) Iron(III) Fe(H₂O)₃(OH)₃ (s) brown ppt (may look orange-brown)
Action of an excess of NH₃ (aq) Iron(III) No further change
Action of Na₂CO₃ (aq) Iron(III) Fe(H₂O)₃(OH)₃ (s) brown ppt (may look orange-brown) and CO₂ gas evolved
Aqueous Ion Aluminium(III) [Al(H₂O)₆]³⁺ (aq) colourless solution
Action of NaOH Aluminium(III) Al(H₂O)₃(OH)₃ (s) white ppt
Action of an excess of NaOH (aq) Aluminium(III) [Al(OH)₄] ⁻ (aq) colourless solution
Action of NH₃ (aq) Aluminium(III) Al(H₂O)₃(OH)₃ (s) white ppt
Action of an excess of NH₃ (aq) Aluminium(III) No further change
Action of Na₂CO₃ (aq) Aluminium(III) Al(H₂O)₃(OH)₃ (s) white ppt and CO₂ gas evolved
Aqueous Ion Cobalt(II) [Co(H₂O)₆]²⁺ (aq) pink solution
Action of NaOH Cobalt(II) Co(H₂O)₄(OH)₂ (s) blue ppt
Action of an excess of NH₃ Cobalt(II) [Co(NH₃)₆]²⁺ (s) pale brown solution
Action of Na₂CO₃ (aq) Cobalt(II) CoCO₃ (s) purple ppt
Action of HCl Cobalt(II) [CoCl₄]²⁻ (aq) blue solution
Variable Oxidation States V(V) [VO₂(H₂O)₄]⁺ yellow solution
Variable Oxidation States V(IV) [VO₂(H₂O)₅]²⁺ blue solution
Variable Oxidation States V(III) [V(H₂O)₆]³⁺ green solution
Variable Oxidation States V(II) [V(H₂O)₆]²⁺ purple solution
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