C7.1 - Green chemistry

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What are bulk chemicals? Chemicals made on a huge scale, thousands of tonnes a year.
What are fine chemicals? Chemicals made on a comparatively small scale.
What 6 things is the chemical industry doing to become more sustainable? Going renewable, improving atom economy, anti-hazardous chemicals, efficient energy usage, waste reduction, preventing pollution.
What are the 5 raw materials for the chemical industry? Crude oil, air, water, vegetable materials, rocks and minerals.
What is a feedstock? Chemical(s) fed into a process in the chemical industry.
What is synthesis and where does it take place? The combination of components or elements to form a connected whole takes place in the reactor.
What products leave the reactor, generally? The desired product, by-products and unchanged products.
What five main types of product are made in the chemical industry? Basic inorganics, petrochemicals and polymers, dyes and paints, pharmaceuticals, specialty chemicals.
Why did people begin to worry about the industry in the late 20th century? Worry over health and environmental impacts of new chemicals.
What percentage of crude oil is used for making chemicals and where does the rest go to? 3% is used for chemicals, and the rest is burnt as fuel or used to make lubricants.
What new type of polyester is made using organic materials? Sorona is made from fermenting renewable plant materials.
What is percentage yield? A measure of a process's efficiency - the actual yield over the theoretical yield.
What is the first step to reacting masses? Write down the balance symbol equation.
What is the second step to reacting masses? Work out the relative formula mass of each reactant and relevant product.
What is the third step to reacting masses? Write down the relative reacting masses under the balanced equation, taking into account any numbers used to balance the equation - eg 2CaO would be 2x56.
What is the fourth step to reacting masses? Convert to reacting masses by adding the units - eg kg or g.
What is the fifth and final step to reacting masses? Scale the quantities to those actually used in the synthesis/experiment.
What two words mean 'a measure of the efficiency of a chemical process given in a percentage' and how is this worked out? 'atom economy' is worked out by dividing the mass of atoms in the product by those in the reactants, and doing x100.
What is used to work out atom economy numerically? relative atomic mass
What are reactive intermediates? Chemicals made to be used in making more chemicals.
Weed-killer producers used to use a highly toxic chemical in their process - what chemical? Hydrogen cyanide
Making polycarbonate plastics used to use an exceedingly dangerous gas that has been used before as poisonous gas. What gas was this? The gas phosgene.
What five main uses are there for energy in a chemical plant? Raising the temperature of reactants, heating mixture to separate/purify them, to dry product material, to process waste material, to transport materials around the plant.
What kind of process gives out energy and which kind takes it in? exothermic gives out, endothermic takes in
What benefit is there of using a catalyst? It speeds up the formation of desired products but not by-products, which means less waste. It also takes less energy per product, because it takes less time so needs less heating etc.
What is being developed in the place of normal catalysts and why? Some biocatalysts are being made, as they work at lower temperatures and set pHs.
What is it called when a product becomes the material for making the same product again? closed-loop recycling
What differences are there between sustainable development and green chemistry? Sustainable development is a plan to meeting today's needs without reducing resources for tomorrow. Green chemistry is a way of thinking about the long and short term effects of things on the environment and on our health.
What good example is there of a drug whose environment impact was reduced, and what two things were improved in the new method of manufacture? The new method for making Ibuprofen has a reusable catalyst and a higher atom economy, so less waste.
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