Why is benzene less reactive than alkenes?

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A-Level (Module 6) Chemistry Fichas sobre Why is benzene less reactive than alkenes?, creado por Fauzia Ali el 08/02/2017.
Fauzia Ali
Fichas por Fauzia Ali, actualizado hace más de 1 año
Fauzia Ali
Creado por Fauzia Ali hace casi 8 años
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Why is benzene less reactive than alkenes?
In cyclohexene the pi bond is made by sideways overlap of p orbitals on adjacent carbon atoms. Whereas for benzene, the pi bond is made by the sideways overlap of p orbitals on all 6 carbons atoms adjacent to each other Therefore on benzene the 6 pi electrons are delocalised over 6 carbon atoms On cyclohexane the two pi electrons are localised between the two carbon atoms
Therefore cyclohexene has a higher pi electron density than benzene and will attract electrophiles more strongly as it induces a bigger dipole So alkenes are more reactive than benzene
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