Introduction to Stereochemistry

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Investigative Organic Chemistry Flashcards on Introduction to Stereochemistry, created by Hashala Fernando on 10/08/2016.
Hashala  Fernando
Flashcards by Hashala Fernando, updated more than 1 year ago
Hashala  Fernando
Created by Hashala Fernando over 8 years ago
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Question Answer
Stereochemistry study of of the spatial (3D) arrangements of atoms in a molecule and how the shape of a molecule affects its chemical reactivity.
Molecular geometry around carbon atom Molecular geometry of carbon is determined by the bonding state.
Flying wedge representation Solid line- atoms which lie in the plane of the paper Solid wedge- bonds towards you Hashed wedge- bonds away from you
Sawhorse representation view C-C bond from an oblique and and indicate the spatial orientation by indicating all C-X bonds including C-H.
Newman projection used to represent alkanes of more than two C and also cycloalkanes.
Fisher projection verticle lines- bonds going away from the viewer horizontal lines- bonds coming towards the viewer.
Isomers compounds which have the same molecular formula but different structures or 3D geometry.
Stereoisomers compounds which have the same molecular formula, same connectivity of atoms but different 3D geometry.
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