Chapter 15- Ideal gases

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Mind Map on Chapter 15- Ideal gases, created by Connor O'Hare on 22/11/2017.
Connor O'Hare
Mind Map by Connor O'Hare, updated more than 1 year ago
Connor O'Hare
Created by Connor O'Hare almost 7 years ago
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Resource summary

Chapter 15- Ideal gases
  1. An ideal gas is a theoretical model that includes assumptions to simplify the behaviour of real gases
    1. There are 6 main assumptions
      1. 1) Fixed volume
        1. 2) Large number of atoms/molecules with random directions + speed
          1. 3) Volume of atoms in gas<<<volume of gas
            1. 4) All collisions are perfectly elastic
              1. 5) Time taken for collisions are negligible
                1. 6) No electrostatic interaction
                2. These assumtions explain how atoms/molecules in an ideal gas cause pressure
                  1. Pressure arises from force due to atoms/molecules change in momentum as they bounce of container walls F=Δp/Δt
                3. Mass- "Amount of matter"
                  1. Kg
                  2. Moles- "The amount of substance that contains as many elementary entities as there are atoms in 12g of carbon-12"
                    1. mol
                      1. (N) Number of atoms or molecules= (n) Number of moles * (NA) Avagadro's constant
                        1. Avagadro's constant=6.02*10^23
                      2. Molar mass- "The mass of one mole of a substance"
                        1. (m) Mass of substance= (n) Number of moles * (M) Molar mass
                        2. Gas laws
                          1. 1) When temperature & mass of gas remain constant then... pV=constant
                            1. Boyle's law
                            2. 2) When volume & mass of a gas remain constant then... p/T=constant
                              1. This relationship allows us to estimate absolute zero
                              2. Combining the gas laws 1 & 2 gives (pV)/T=constant
                                1. Equation of state of an ideal gas
                                  1. pV=nRT
                                    1. Molar gas constant (8.31JK^-1mol^-1
                                  2. Average velocity of particles in a gas =0ms^-1
                                    1. To describe the motion of particles inside the gas we use the root mean square speed (r.m.s speed)
                                      1. Maxwell-Boltzmann distribution
                                        1. "The distribution of the speed of particles in a gas"
                                          1. Changing the temperature, changes the distribution
                                            1. The hotter the gas becomes, the greater the range of speeds and the distribution becomes more spread out
                                          2. (k) Boltzmann constant= (R) Molar gas constant / (NA) Avagadro's constant
                                            1. pV=NkT
                                              1. Kinetic energy=(3/2)kT
                                                1. Kinetic energy∝Temperature
                                                  1. At a given temperature, atoms and molecules in different gases have the same kinetic energy. However because their masses are different, their r.m.s speeds will be different
                                                    1. For an ideal gas all the internal energy is completely in the form of kinetic energy
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