DEFINITION: the state of dynamic balance
where the rate of the forward
reaction equals the rate of the
backwards reaction
Dynamic- when
the 2 reactions are
still occurring
once the reaction reaches equilibrium there is
no change in the concentration of reactants or
products
both reactants and products will be
present @ equilibrium
concentration of products @ equilibrium depends on
the reaction itself and the conditions
Le Chatelier's principal
DEFINITION- if a stress is applied to a
system the system reacts
(readjusts) to relieve the
stress
Pressure increases - goes to the side with less moles
pressure decreases- goes to the side with the greater no.
of moles
pressure only has an effect if
both substances are gases
different no.s
of moles on
each side of the
equation
Temperature increase - endothermic reaction occurs
Temperature decrease -exothermic reaction occurs
Concentration X increases - goeses to remove X
Concentration X decreases- goeses to increase X
Expt.
Industrial applications of Le
chartseliers principle
The haber process
ammonia manufucturing
Pressure - high pressure the reactions goeses to the right
but it is expensive to maintain and potentially dangerous
a compromise is reached @ 200 atmospheres
Temperature- low temp, the reaction sides to the right
but this will make the reaction slow a compromise is
reached @ 500 degrees
The contact process
manufacturing of sulfuric acid
Pressure - high pressure increases the yield
but is carried out just above atmospheric
pressure
Temperature - low temp. favours the
production of SO3 but a compromise is
reached @ 450 degrees