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4273174
DF4
Description
Salters A level advanced chemistry, Df4 topic, " where does energy come from ?".
No tags specified
chemistry a level
bond enthalpies
bonds
chemistry
fuels
fuel
a level
df4
enthalpy
bond length
chem
a level
Mind Map by
James Howlett
, updated more than 1 year ago
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Created by
James Howlett
almost 9 years ago
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Resource summary
DF4
Bond enthalpies
Chemical bond = electrical attraction between atoms or ions
Bond enthalpy = Qunatity of energy required to break a particular bond in a molecule
Bond enthalpy will be a negative value if exothermic
Greater the bond enthalpy the stronger the bond
Equilibrium bond length = Attractive and opposing forces with in bond are equal
Shorter bond length = stronger bond
Double bond = high B.E Triple bond = V.high B.E
Average bond enthalpies used; exact value is dependent on particular compound bond is found.
Bond enthalpies measured indirectly using enthalpy cycles
Usefull links
http://www.lisgar.net/magwood/sch4u%20bonding%203.htm
http://www.chemguide.co.uk/physical/energetics/sums.html
Breaking and making bonds
CH4 + 2 O2 = CO2 + 2 H2O
ΔH = -890 KJmolmol-1
Is breaking bonds and creating new ones
Worked out by looking at structure of reactants and products
Always refers to breaking a bond in a gaseous compound
Combustion of methane = exothermic
energy in bond-breaking steps < energy in bond-making
Not all have to be broken to form new ones
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