Gravimetric and Volumetric Analysis

Descrição

FlashCards sobre Gravimetric and Volumetric Analysis, criado por reidk em 16-09-2013.
reidk
FlashCards por reidk, atualizado more than 1 year ago
reidk
Criado por reidk quase 11 anos atrás
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Resumo de Recurso

Questão Responda
Gravimetric Precipitate properties 1. Have a known formula 2. Have low solubility 3. Remain stable as heated 4. Be the product of one specified reaction (inert)
Steps in measuring water content 1. Weigh the sample 2. Heat the sample in an oven at 110 degrees 3. Allow sample to dry 4. Reweigh (and repeat until mass is constant)
Steps in Gravimetric Analysis 1. Weigh the sample 2. Mix sample in water to dissolve soluble ion 3. Filter to remove impurities 4. Add excess reagent to form a specific precipitate 5. Filter precipitate and wash with water 6. Dry precipitate at 100 degrees 7. Weigh the precipitate (repeat 6 and this step until at constant mass)
Errors in Gravimetric - Loss of some precipitate (under) - Incomplete precipitation (under) - Decomposition of samples during drying to form gases (under) - Incomplete drying (over) - Presence of contaminants (over) - Adsorption of ions in solution on surface of precipitate (over) - Formation of other precipitates (over)
Primary Standards and standard solutions A primary standard is a substance so pure that its amount (mol) can be determined from its mass A standard solution is a solution with a known concentration that is prepared from a primary standard
Criteria of primary standards - It is obtainable in pure form - It has a known formula - Does not react with the atmosphere - It has a high molar mass to minimise weighing errors - cheap and readily available - highly soluble
Steps in Volumetric Analysis 1. A burette is filled with standard solution 2. Our unknown is delivered into a conical flask with a known volume 3. Indicator is added 4. The end point is found
Acid-Base titration equivalence points - Strong acid, Strong base: pH of 7 - Weak acid, Strong base: approx pH of 9 - Strong acid, Weak base: approx pH of 5 - Weak acid, weak base: back titration because of the slow rate of the reaction
Back Titration 1. Find the amount in mol of common solution in secondary (excess) reaction 2. Find the amount in mol of common added initially 3. Find the amount in mol reacting (initial - excess) 4. Consider dilution factors, move back from aliquot to flask (flask/aliquot x mol) 5. Work out calculations as asked

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