Questão | Responda |
First ionisation energy | energy needed to remove one mole of electrons from one mole of gaseous atoms |
relative atomic mass | average mass of an atom of an element compared to 1/12 of one atom of Carbon-12 |
second ionisation energy | energy needed to remove one mole of electrons from one mole of unipositive ions |
empirical formula | simplest whole number ratio in which atoms of each element are found in a compound |
covalent bond | pair of electrons shared between two atoms |
metallic bond | attraction between a cation and a sea of de-localised electrons |
electronegativity | the ability of an atom to attract electrons towards itself in a covalent bond |
homologous series | series of compounds with the same functional group but differs by -CH2 each time |
structural isomerism | same molecular formula, different structural fomula |
chain isomerism | same molecular formula, different carbon arrangement |
positional isomerism | same molecular formula, functional group in a different position |
functional group isomerism | same molecular formula, different functional group |
initiation (free radical substitution) | production of free radicals breaks homolytically photochemical reaction |
propagation (free radical subs) | reaction between a free radical and a molecule to make another free radical |
termination (free radical subs) | reaction between two free radicals making an unreactive molecule |
standard enthalpy of formation | enthalpy change when one mole of a compound is formed from its constituent atoms in their standard states, in standard conditions |
mean bond enthalpy | standard molar enthalpy change of bond dissociation is the energy required to break a specific covalent bond. this varies from compound to compound, so an average is used |
standard enthalpy of combustion | enthalpy change when one mole of a compound is completely burnt in oxygen under standard conditions |
enthalpy change | heat energy change measured at constant pressure |
Hess's law | the enthalpy change of a reaction is independent on the route (pathway from reactants to products) |
disproportionation | redox reaction in which the oxidation number of some atoms of a particular element increase and others decrease |
geometrical isomer | same structural formula, but bonds arranged differently in space |
inductive effect | the effect on electron density in one portion of a molecule due to electo/nucleophiles elsewhere. causes dipoles and effects stablity |
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