CHEM 1

Descrição

Flashcards to summarise the AQA CHEM 1 topics included on the syllabus
Lucy Denver
FlashCards por Lucy Denver, atualizado more than 1 year ago
Lucy Denver
Criado por Lucy Denver mais de 10 anos atrás
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Resumo de Recurso

Questão Responda
First Ionisation Energy equation X(g)>>>>X+(g) +e-
Mass Spectrometer stages Vapourise Ionise Accelerate Deflect Detect
Atomic Radius ACROSS DECREASES Nuclear charge increases but electrons are added to the same energy level, therefore, greater EFA between nucleus and outermost electrons
Atomic Radius DOWN INCREASES Electrons are added to different energy levels further from the nucleus, reducing EFA and shielding of charge also increases
First Ionisation Energy DOWN DECREASES
First Ionisation Energy ACROSS INCREASES GENERALLY
First Ionisation Energy blips Electrons in higher energy subshells OR Spin pair repulsion between paired negative electrons
Relative mass of an electron 1/1840
Moles in solution Moles= volume x concentration
Moles in solid Moles = mass / mr
Ideal Gas Equation pV = nRT p in pa v in m^3 t in K
Degrees to Kelvin +273
Empirical formula % or mass / by Ar / by smallest use ratio
Empirical to molecular n = mr of molecule / mr of empirical empirical x n = molecular formula
Atom economy mass of product / mass of all reactants x 100
Yield actual mass / theoretical mass x 100
Ionic bond Strong EFA between oppositely charged ions
Ionic are soluble in water Polar solvent molecules attract ions out of the lattice into solution
Metallic bond Strong EFA between positive metal ions and delocalised electrons
Covalent bond A shared pair of electrons between two atoms
Giant covalent structures Silicon dioxide Graphite Diamond
Dative covalent bond A covalent bond where both of the shared electrons are donated from one of the atoms
Van der Waal's depends on... Size of molecules - more electrons means larger dipoles which are harder to overcome which INCREASES mbp Branching - more branching decreases surface contact area and vdw which DECREASES mbp
Hydrogen bond H bonded to an O, N or F with at least one lone pair
2 Bonding Pairs Linear 180°
3 Bonding Pairs Trigonal Planar 120°
4 Bonding Pairs Tetrahedral 109.5°
5 Bonding Pairs Trigonal Bipyramidal 120° and 90°
6 Bonding Pairs Octahedral 90°
1 Lone Pair 2 Bonding Pairs Angular 117.5°
1 Lone Pair 3 Bonding Pairs Pyramidal 107°
2 Lone Pairs 2 Bonding Pairs Bent 104.5°
2 Lone Pairs 4 Bonding Pairs Square Planar 90°
Structural Isomers Chain Isomerism Position Isomerism Functional Group Isomerism
Fractional Distillation Separates alkanes into chain lengths by bp HOT BOTTOM and COLD TOP LONG BOTTOM and SHORT TOP
LPG Camping gas
Naptha Petrochemicals
Kerosene Jet fuel
Diesel Central heating fuel
Mineral oil Lubricant
Fuel oil Power station fuel
Wax, grease Candles
Bitumen Road surfacing
What is Cracking? Breaking C-C alkane bonds to form an alk-1-ene and shorter chained alkane
Thermal Cracking conditions ONE ALKENE PRODUCT 1000K 7000KPa No catalyst
Catalytic Cracking BRANCHED ALKANES (burn smoothly as fuels), CYCLOALKANES AND AROMATICS 720K Just above atmospheric pressure Zeolite catalyst
Complete alkane combustion Alkane + Oxygen>>>> Carbon Dioxide + Water
Incomplete alkane combustion Alkane + Oxygen >>>> Carbon Monoxide + Water Alkane + Oxygen >>>> Carbon + Water
Nitrogen Oxides Formed as air petrol mixture sparks and explodes Nitrogen + Oxygen >>>> Nitrogen Monoxide
Catalytic Converter PLATINUM, PALLADIUM, RHODIUM Spread thinly over ceramic honeycomb to give large surface area 2CO + 2NO >>>> N2 + 2CO2 NO + Alkane >>>> CO2 + Water + N2
Sulphur dioxide pollutant Under UV SO2 + 1/2 O2 >>>> SO3 SO2 OR SO3 + Water >>>> Acid Rain NOT REMOVED IN CATALYTIC CONVERTER
Flue Gas Desulphurisation Use Calcium Carbonate (limestone) to neutralise SO2

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