Organic Chemistry (Aliphatic)

1. Formation
   1. Oxidation of Aldehydes
   2. Hydrolysis of Esters, AC, nitriles, amides
2. P.Prop
   1. H-bond → soluble in organic solvents and water
3. RCOOH + PCL5 → RCOCl + POCl3 + HCl
   1. Formation of Acyl Chloride (RCOCl)

1. Formation
   1. C.A + A: Reflux, Strong acid
   2. AC/AA + A: Reflux, Dry
      1. AA less reactive → slower, less toxic, less exothermic
2. C.Prop
   1. Relatively unreactive
3. Hydrolysis break O bridge
   1. Acidic: Reversible
   2. Basic: 1D, Water soluble ionic salt formed, then react with HCl
4. Uses
   1. Nice smell
   2. Solvent
   3. Plasticisers
   4. Saponification - Alkaline Hydrolysis of triglycerol esters
   5. Biodiesel

1. Hydrolysis
   1. +H2O → RCOOH + NH3
   2. +HCl → RCOOH + NH4Cl
   3. +NaOH → RCOONa + NH3
2. Reduce to primary amines

1. Formation
   1. Oxi of primary Alcohols
   2. Reduction of CA
2. Easily oxidised

1. Oxi of secondary alcohols
2. Resistant to oxidation

1. +Amines → N-substituted amides
2. +Ammonia → Amide
3. → Esters

Anexos:

• Organic compounds