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4230566
ELECTROLYSIS
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gcse
chemistry unit 2
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Connie Blackburn
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Connie Blackburn
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Resumo de Recurso
ELECTROLYSIS
WHAT IS ELECTROLYSIS?
The decomposition of a compound using electricity.
Negative electrode-cathode
Positive electrode-anode
Compound must be molten not solid!
HOW DOES LEAD BROMIDE DECOMPOSE?
Lead Bromide - Lead + Bromine Gas
oppositely charged ions are attracted to oppisetly charged electrodes;
CATIONS ARE POSITIVE IONS (metal ions and hydrogen).
ANIONS ARE NEGATIVE IONS (non-metal ions).
SUMMARY
All ionic compounds when molten can be decomposed using electrolysis.
Cations travel to the cathode.
Anions travel to the anode
Non-metal always forms at the anode.
The metal and hydrogen always forms at the cathode.
The molten substance been electrolysed is called the electrolyte.
The electrodes do not involve themselves with the reaction because of the material.
THE ELECTROLYSIS OF SOLUTIONS
products from the salt solution will be different to the molten solution because there is water, which produces ions.
During electrolysis, these ions compete with the metal and non-metal ions
The more reactive a metal is the more it prefers being ions.
If a less reactive metal, such as copper or silver is present it would rather accept the electrons than H+.
Hence, the metal forms at the cathode
THE ELECTROLYSIS OF SALTY WATER
This industry has been based around the electrolysis of brine, salty water
Brine - Sodium Hydroxide + Chlorine + Hydrogen
At the Cathode-Hydrogen bubbles off
At the Anode- Chlorine bubbles off
Na+ and OH- ions are left behind, which means a solution of sodium hydroxide forms.
products from the electrolysis of brine
sodium hydroxide
soaps, detergents and paper
Chlorire
solvents, bleach, drugs, hydrochloric acid , paints and dyes
Hydrogen
fuel for rockets and nylon.
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