Fundamental Ideas for Chemistry- Atoms

Atoms and elements All substances are made of tiny particles called atoms. An element is a substance that is made of only one sort of atom. There are about 100 different elements. These are shown in the periodic table, which is a chart with all the elements arranged in a particular way. The horizontal rows in the periodic table are called periods and the vertical columns are called groups. The elements in a group have similar properties to each other. Metals and non-metals The metals are shown on the left of the periodic table, and the non-metals are shown on the right.  Chemical symbols The atoms of each element are represented by a chemical symbol. This usually consists of one or two different letters, but sometimes three letters are used for newly discovered elements. For example, O represents an oxygen atom, and Na represents a sodium atom.The first letter in a chemical symbol is always an UPPERCASE letter, and the other letters are always lowercase. So, the symbol for a magnesium atom is Mg and not mg, MG or mG. Atomic structure Structure of the atom All substances are made from tiny particles called atoms. An atom has a small central nucleus made up of smaller sub-atomic particles called protons and neutrons. The nucleus is surrounded by even smaller sub-atomic particles called electrons. Protons and electrons have an electrical charge. Both have the same size of electrical charge, but the proton is positive and the electron negative. Neutrons are neutral. A summary of the electrical charges in sub-atomic particles The number of electrons in an atom is equal to the number of protons in its nucleus. This means atoms have no overall electrical charge. Atomic number and mass number The atomic number of an atom is the number of protons it contains. All the atoms of a particular element have the same atomic number (number of protons). The atoms of different elements have different numbers of protons. For example, all oxygen atoms have 8 protons and all sodium atoms have 11 protons.The mass number of an atom is the total number of protons and neutrons it contains. The mass number of an atom is never smaller than the atomic number. It can be the same, but is usually bigger. Full chemical symbols You need to be able to calculate the number of each sub-atomic particle in an atom if you are given its atomic number and its mass number. The full chemical symbol for an element shows its mass number at the top, and its atomic number at the bottom. This symbol tells you that the chlorine atom has 17 protons. It will also have 17 electrons, because the number of protons and electrons in an atom is the same.The symbol also tells you that the total number of protons and neutrons in the chlorine atom is 35. Note that you can work out the number of neutrons from the mass number and atomic number. In this example, it is 35 – 17 = 18 neutrons. Electronic structure The electrons in an atom occupy energy levels. These are also called shells. Each electron in an atom is found in a particular energy level. The lowest energy level (innermost shell) fills with electrons first. Each energy level can only hold a certain number of electrons before it becomes full. The first energy level can hold a maximum of two electrons, the second energy level a maximum of eight, and so on. Electrons in the first three energy levels for the elements with atomic numbers 1 to 20 In the first shell, there can only be two electrons, in the second there can be eight, in the third eight is the maximum and that it the amount that you need to know for GCSE. Writing an electronic structure The electronic structure of an atom is written using numbers to represent the electrons in each energy level. For example, for sodium this is 2,8,1 – showing that there are: 2 electrons in the first energy level 8 electrons in the second energy level 1 electron in the third energy level. You can work out the electronic structure of an atom from its atomic number or its position in the periodic table. Start at hydrogen, H, and count the elements needed to reach the element you are interested in. For sodium, it takes: 2 elements to reach the end of the first period (row) 8 elements to reach the end of the second period 1 element to reach sodium in the third period. The diagram of the periodic table shows how this works. Periodic table related to electronic structure You need to be able to write the electronic structure of any of the first twenty elements (hydrogen to calcium). Electronic structure diagrams You need to be able to draw the electronic structure of any of the first twenty elements (hydrogen to calcium). In these drawings: the nucleus is shown as a black spot each energy level is shown as a circle around the nucleus each electron is shown by a dot or a cross. The electronic structure of some elements lithium Li 2,1fluorine F 2,7chlorine Cl 2,8,7calcium Ca 2,8,8,2Do not worry in the exam about colouring in the electrons. Just make them clear and ensure they are in the right place. You may be asked to use a cross rather than a dot for each electron. Working out an element's electronic structure Here is how to use the periodic table to work out an electronic structure: Find the element in the periodic table. Work out which period (row) it is in, and draw that number of circles around the nucleus. Work out which group the element is in and draw that number of electrons in the outer circle – with eight for Group 0 elements – except helium. Fill the other circles with as many electrons as needed. Remember – two in the first circle, and eight in the second and third circles. Finally, check that the number of electrons is the same as the atomic number.

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