Reaction Conditions Quiz F324

Description

GCE Chemistry (F324 - Polymers and Synthesis) Quiz on Reaction Conditions Quiz F324, created by sophie.holland96 on 16/05/2014.
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Quiz by sophie.holland96, updated more than 1 year ago
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Created by sophie.holland96 over 10 years ago
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Resource summary

Question 1

Question
What are the reaction conditions for the bromination (halogenation) of benzene?
Answer
  • Br2
  • Br2 / FeBr3
  • Br2 / HCl

Question 2

Question
What are the reaction conditions for the nitration of benzene?
Answer
  • Conc HNO3, Conc HCL, 50 degrees
  • Conc HNO2, Conc HCl, 40 degrees
  • HNO3, HCL 10 degrees

Question 3

Question
What are the conditions for making phenylamine from nitrobenzene?
Answer
  • Sn catalyst/conc HCl
  • Sn catalyst/conc HCl and reflux
  • Fe catalyst and reflux

Question 4

Question
Select the correct conditions below for diazotisation (creating a benzenediazonium ion from phenylamine)
Answer
  • NaNO2
  • HCl (aq)
  • below 10 degrees
  • below 20 degrees
  • H2SO4
  • Chlorine gas
  • HNO3

Question 5

Question
The conditions for creating an azo dye are... Phenol and acidic
Answer
  • True
  • False

Question 6

Question
How can you make sodium phenoxide from phenol?
Answer
  • Add NaOH
  • Add Na
  • Add NaNO3
  • Add chlorine

Question 7

Question
How do you make an aldehyde from a primary alcohol?
Answer
  • Oxidise with acidified potassium dichromate. Example of an acid could be sulphuric acid. Reflux
  • Oxidise with Tollen's reagent. And sulphuric acid. Distil.
  • Oxidise with acidified potassium dichromate. Example of an acid could be sulphuric acid. Distil immediately.

Question 8

Question
How do you reduce an aldehyde/ketone to form an alcohol?
Answer
  • Add NaBH4
  • Add NaBH4 , ensure the mixture is aqueous.
  • Add HCL and alcohol

Question 9

Question
How do you reduce an aldehyde/ketone to form an alcohol?
Answer
  • Add NaBH4
  • Add NaBH4 , ensure the mixture is aqueous.
  • Add HCL and alcohol

Question 10

Question
How would you oxidise a secondary alcohol to a ketone?
Answer
  • Reflux with acidified potassium dichromate (suitable acid would be sulfuric).
  • Reflux with hydrochloric acid
  • Add NaBH4 (aq) and warm

Question 11

Question
How would you test for an aldehyde using Tollen's reagent (ammoniacal silver nitrate)?
Answer
  • Make Tollen's reagent fresh using silver nitrate, add sodium hydroxide to form a precipitate and then just dissolve the precipitate using ammonia. Add your aldehyde to the solution of Tollen's, warm the mixture, and observe the formation of a silver mirror (precipitate).
  • Make Tollen's reagent fresh using silver nitrate, add sodium hydroxide to form a precipitate and then just dissolve the precipitate using ammonia. Add your aldehyde to the solution of Tollen's, and observe the formation of a silver mirror (precipitate).
  • Add your aldehyde to the solution of bottled Tollen's reagent, and observe the formation of a silver mirror (precipitate).

Question 12

Question
How would you make an ester?
Answer
  • Add alcohol and carboxylic acid. In the presence of a sulfuric acid catalyst. Reflux
  • Add alcohol and carboxylic acid. In the presence of a sulfuric acid catalyst.
  • Add alcohol and carboxylic acid. In the presence of a sulfuric acid catalyst. Distil
  • Add alcohol and acid. In the presence of a sulfuric acid catalyst.
  • Add alcohol and carboxylic acid. In the presence of a nitric acid catalyst.

Question 13

Question
How would you go about conducting acid hydrolysis of an ester?
Answer
  • Ensure an excess of water, Dilute HCl catalyst, Reflux
  • Ensure an excess of water, Dilute NaOH Reflux
  • Dilute HCl, Reflux

Question 14

Question
How would you go about conducting an alkaline hydrolysis on an ester?
Answer
  • Aqueous NaOH, Reflux
  • HCl
  • NaOH Distil

Question 15

Question
How would you convert a halogenoalkane to an alcohol?
Answer
  • Add NaOH/water,
  • Add NaOH, Reflux
  • Add NaOH/water, Reflux

Question 16

Question
How would you make an aliphatic amine from a halogenoalkane?
Answer
  • Add excess ammonia, in an ethanol solvent, and reflux
  • Add excess ammonia, in an ethanol solvent
  • Add ammonia, in an ethanol solvent, and reflux
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