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Created by I Shouldn't be awake
over 6 years ago
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Question | Answer |
What are stereoisomers? | molecules with same connectivity but different spatial arrangement |
What type of stereoisomerism do complex ions exhibit? | Cis-Trans Optical |
What conditions are required for stereoisomerism in square planar structures? | 4 co-ordinate bonds 2 different monodentate ligands |
How do complex ions bend the rules of cis-trans stereoisomerism? | In organic meant to have C=C Not necessary for complex ions |
Arrangement of ligands in square planar structures | Ligands are arranged in the same plane at the corners of a square with 90' bond angles |
Arrangements of identical ligands in cis-isomerism of square planars | Two identical groups are adjacent to each other 90' apart |
Arrangement of identical ligands in trans- square planar | Identical ligands are opposite each other 180' apart |
Optical isomerism only occurs in what? What conditions must be met? | octahedral complexes Must have 2 or more bidentate ligands |
How does cis-platin work? | Forms Pt complex in cell Binds to DNA Prevents DNA replication Triggers apoptosis |
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