Naming heterocycles

Description

Heterocyclic and Pericyclic Chemistry Mind Map on Naming heterocycles, created by al44 on 04/12/2013.
al44
Mind Map by al44, updated more than 1 year ago
al44
Created by al44 almost 11 years ago
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Resource summary

Naming heterocycles
  1. Named rings
    1. Hantzsch-Widman System
      1. Heteroatoms at begining
        1. 1. O oxa
          1. 2. S thia
            1. 3. Se selena
              1. 4. Te tellura
                1. 5. N aza
                  1. 6. P phospha
                    1. 7. As arsa
                      1. 8. Sb stiba
                        1. 9. Si sila
                          1. 10. Ge germa
                            1. 11. B bora
                            2. Endings indicate ring size and degree of saturation
                              1. Ring size
                                1. 3- ir
                                  1. 4- et
                                    1. 5-ol
                                      1. 6- i/a
                                        1. 7- ep
                                          1. 8- op
                                          2. No N
                                            1. un sat
                                              1. e/ene/ine
                                              2. 2H
                                                1. ane
                                              3. N present
                                                1. un sat
                                                  1. e/ine/ane
                                                  2. 2H
                                                    1. ine
                                              4. Fused heterocycles
                                                1. Determine senior ring
                                                  1. N present in one ring only then senior
                                                    1. If not...
                                                      1. Highest atom priority
                                                          1. Larger>Smaller
                                                            1. Ring with most heteroatoms
                                                              1. Same size ring same number of atoms- highest priority heteroatoms
                                                                1. Same size ring, number and nature- Lowest numbering
                                                  2. Multiple fusion
                                                    1. Align maximum number of rings horizontal and any extra pointing to the top right
                                                      1. Start numbering from most anticlockwise position on top right ring
                                                        1. Between 1 and 2 side is a etc.
                                                          1. [1,2-a]
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