unit 5 thermodynamics

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flashcards for the test
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Error in calorimeter experiment of combustion of ethanol not all heat produced was transferred to the water. water loses some heat to the surroundings. incomplete combustion of ethanol
Definie Hess's law the enthalpy change occurs, for any reaction independent of the route, provided the initial and final conditions.
Defnie Standar enthalpy of formation the enthalpy change that occurs, when one mole of substance is formed from its element in standard conditions. product-reactant
describe the endothermic process breaking bonds, atoms are separated, which are attracted by electrostatic forces. Thus, needing energy. Reactants more stable than product. But enthalpy of the product is stronger. T decreases.
describe the exothermic process bonds forming, so atoms are bonded together, which are attracted by electrostatic forces. Thus, releasing energy. T decreases products more stable than reactants. ENthaply of reactants greater.
standard enthaply of combustion is the enthalpy change that occurs, when one mole of a substance is combusted in oxygen under standard conditions. reactants - products.
Emergy cycles Born haber cycle. atom and I.E atomization: is the enthalpy change that occurs when one mole of a gaseous atom is formed from its element. I.E: is the minimum energy needed to remove one mole of gaseous electron from one mole of gaseous atom. Na+ -> Na + e-
Energy cycles Born Haber cycle. E.A and Lattice enthalpy E.A: is the enthalpy change that occurs when one mole of gaseous electron is added to one mole of gaseous atom. Cl-> Cl- +e- L.E: is the enthalpy change that occurs when one mole of solid ionic compound is separated from a gaseous ion under standard conditions.
Predicting the Lattice Enthaply The higher the lattice enthalpy, as the ionic radius decreases and the ionic charge increases.
Enthalpies change of solution is the enthalpy change that occurs when one mole of a solute is dissolved in a solvent to infinite dilution under standard conditions. ionic compounds are soluble in water, as ions are attracted to the polar solvent water. Hsol=Hhdry + HL.E
define entropy (s) refers to the distribution of available energy among particles. the higher the distribution of available energy the higher the entropy.
predicting entropy change values s-> g entropy increases, as the distribution of energy is increasing, therefore the entropy is positive.
calculating the entropy change s = product - reactant
Gibbs free energy (system) predicts the feasibility of a reaction = H - TS
calculating gibbs free energy reaction Gproduct - Greactant
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