Section 2: Electromagnetic Radiation and Quantum Phenomena

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The photoelectric effect, energy levels, photon emission, absorption spectra, wave-particle duality
Francesca Wittmann
Flashcards by Francesca Wittmann, updated more than 1 year ago
Francesca Wittmann
Created by Francesca Wittmann almost 8 years ago
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Resource summary

Question Answer
What is the photoelectric effect? The emission of electrons from a metal surface when the surface is illuminated by light of a frequency greater than the threshold frequency
Threshold Frequency The minimum frequency of light needed to cause photoelectric emission
What happens if the incident light is below the threshold frequency? No electrons are emitted
What affects the threshold frequency? The material of the surface e.g. type of metal. The intensity of the light does not affect it!
Why do emitted electrons vary in KE up to a max? Vary in KE as takes some energy to reach surface. Max KE when any excess energy from photon transferred all to the KE of electron
Above the threshold frequency, what happens if you increase the intensity of the incident light? (What does it not do?) Increased emission of electrons per second BUT it DOES NOT increase the KE of the electrons as they can only absorb one photon at a time)
Above the threshold frequency...What does increasing the frequency of the incident light do? Increases the max KE of the emitted electrons
Equation for max KE of photoelectrons Max KE= hf- work function
How would the photoelectric effect be explained by wave theory? It Cant- According to Wave theory: For a particular frequency of light the energy carried is proportional to the intensity and is spread out evenly over the wavefront meaning each electron gains a bit of energy. Therefore increasing intensity and prolonged exposure would result in photo emission. also increasing intensity should increase KE)
Equation for Stopping Potential eVs = KE max (V=E/Q) e= charge on the electron Vs= stopping potential
What energy level is ground state? n=1
When electrons move down energy levels what happens? A photon of energy equivalent to the energy gap is emitted
Proof for discrete energy levels in an atom Spectrum have distinct lines therefore only photons of distinct energies emitted therefore discrete energy levels
What does the energy of each energy level in an atom represent The energy needed to completely remove an electron from that level
What is the ionisation energy of an atom The energy needed to completely remove an electron from the ground state (n=1)
How does a fluorescent tube work? Filled with mercury vapour with a inner coating. Electrons ionise some mercury atoms. Flow of electrons created exciting other mercury atoms. When they de-excite they emit ultraviolet photons. UV absorbed by atoms in coating causing excitation. They de-excite in steps editing visible photons.
What emits a continuous spectrum? Hot things (in the visible and infrared parts) Continuous as electrons are not bound in energy levels
When do you get a line absorption spectrum and what does it look like? When a continuous spectrum passes through a cool gas. Dark lines appear where energy has been absorbed.
What does an emission spectra look like for a particular gas? Dark and then bright lines where photons are emitted
Evidence that light behaves as a wave Diffraction patterns and Interference patterns
Evidence that light behaves as a particle The photoelectric effect
De Broglie equation /\ = h/mv
Evidence for particle nature of Electrons Electron beam can be bent by charged objects
Evidence for wave nature of Electrons Electron Diffraction: diffraction patterns observed when accelerated electrons interact with spaces in graphite crystal. --> increasing speed decreases wavelength i.e. circles squash together towards centre
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