Classified according
to the number of
carbon atoms
3- Triose
5- Pentose
6 - Hexose
Sweet
Di-saccharides
General Formula (C6H1O5)n
2 mono-saccharides
Sweet
Examples: Sucrose, Lactose and Maltose
Joined by a condensation reaction resulting in glycosidic bonds(covalent)
Condensation reaction: two
mono-saccharides join together and
water molecule is removed
Hydrolisis is the opposite reaction to the
condensation reaction which formed the molecule,
so water is added to the di-saccharide to split them
apart into two mono-saccharides.
Poly-saccharides
Long chains of
mono-saccharides
repeated condensation
reactions.
normally 1000's
of monomers
Complex carbohydrates
Not sweet
Poly-saccharides are polymers
formed by glycosidic bonding of
mono-saccharide subunits.
Important poly-saccharides
Starch
Mixture of 2 poly-saccharides -
amylose and amylopectin
Forms solid grains inside plant cells
(often inside chloroplasts)
The branches in amylopectin are
formed by other 1-4 linked chains
joing the main poly-saccharide by
1-6 linkages.
Used as an energy store in
plants
Not soluble
Amylopectin is
branched, amylose
is not.
1-4 linked (linked between carbon
atoms 1 and 4 successive glucose
units) glucose molecule make up the
chains of both poly-saccharides
The chains coil up into a basic
spiral shape making the
molecules compact
Hydrogen bonds hold the
poly-saccharide chain in
the compact shape.
Made of alpha glucose
molecules linked by
glycosidic bonds.
Cellulose
Constitutes on average
20-40% of the plant cell wall.
Made of beta glucose units.
Most abundant organic
molecule - found in plant cell
walls. It is very slow to
decompose.
Enzyme cellulase can break
down cellulose, but it is
relatively rare in nature.
The chains straight, not coiled.
Hydrogen bonding between
mono-saccharide molecules in
the chain gives strength
Hydrogen bonding between
cellulose molecules cause
bundles called microfibrils to
develop. These are held
together in fibres
A cell wall will have several
layers of fibres running in
different directions - gives great
strength almost equal to steel.
Provides support in plants and
stops plant cells bursting.
Freely permeable to water and
solutes
Ruminants
have bacteria in
the gut that are
capable of
breaking down
cellulose
Glycogen
This is the storage poly-saccharide in
animals (equivalent to starch in plants)
Found in the liver and
muscle cells where a energy
store is needed.
Mainly fungi also store glycogen
Forms tiny granules inside
cells which are usually
associated with smooth
endoplasmic reticulum.
Each glycogen molecule contains a
few 1000 glucose units.
Similar in structure to amylopectin- but more
branched i.e made of 1-4 linked alpha glucose
chains with 1-6 linked side branches.
Chitin
Beta glucose 1-4 polymer.
Subunits: derivatives of
beta-glucose called
N-acetylglucosamine.
Abundant structural molecule in arthropod
exoskeletons and fungal cell walls.