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417503
Naming heterocycles
Description
Heterocyclic and Pericyclic Chemistry Mind Map on Naming heterocycles, created by al44 on 04/12/2013.
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heterocyclic and pericyclic chemistry
heterocyclic and pericyclic chemistry
Mind Map by
al44
, updated more than 1 year ago
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Created by
al44
almost 11 years ago
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Resource summary
Naming heterocycles
Named rings
Hantzsch-Widman System
Heteroatoms at begining
1. O oxa
2. S thia
3. Se selena
4. Te tellura
5. N aza
6. P phospha
7. As arsa
8. Sb stiba
9. Si sila
10. Ge germa
11. B bora
Endings indicate ring size and degree of saturation
Ring size
3- ir
4- et
5-ol
6- i/a
7- ep
8- op
No N
un sat
e/ene/ine
2H
ane
N present
un sat
e/ine/ane
2H
ine
Fused heterocycles
Determine senior ring
N present in one ring only then senior
If not...
Highest atom priority
Larger>Smaller
Ring with most heteroatoms
Same size ring same number of atoms- highest priority heteroatoms
Same size ring, number and nature- Lowest numbering
Multiple fusion
Align maximum number of rings horizontal and any extra pointing to the top right
Start numbering from most anticlockwise position on top right ring
Between 1 and 2 side is a etc.
[1,2-a]
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