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7159179
AS Chemistry - OCR - F321
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Chem - Exam 1 revision
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Resource summary
AS Chemistry - OCR - F321
Electronic Structure, Periodic Table and Structure of the Atoms & Isotopes
Inside an atom
Neutron
Proton
Electron
Definitions
Annotations:
Must learn these!
Molecule - How elements come together to complete their outer shell
Ion - An atom with a charge (+/-)
Element - Found on the periodic table
Mixture - 2 or more substances together which haven't reacted
Compound - Same as a mixture but a reaction has taken place
Atom - The smallest part of an element that keeps its chemical properties
THE RELATIVE ISOTOPIC MASS IS THE MASS OF THE ISOTOPE COMPARED TO 1/12 OF THE MASS OF AN ATOM OF CARBON-12
THE FIRST IONISATION ENERGY IS THE ENERGY REQUIRED TO REMOVE ONE ELECTRON FROM EACH ATOM IN 1 MOLE OF GASEOUS ATOMS TO FORM 1 MOLE OF GASEOUS 1+ IONS
Rules:
Molecules = Non-metals
+ Ions = Metals
- Ions = Non-metals
Molecular ions = don't follow these rules
Annotations:
Must learn these
Isotopes
Same number of PROTONS & ELECTRONS
Different number of NEUTRONS
Points That Affect Ionisation Energy
Nuclear Charge
Larger charge - more energy needed
Shielding
More shielding - less energy needed
Distance From the Nucleus
Further from the nucleus - less energy needed
Oxidation Numbers
OXIDATION IS LOSS (of electrons)
REDUCTION IS GAIN (of electrons)
Oxidation is the addition of oxygen
Oxidation is an increase in the oxidation number
CO2 - OxNo: +4 -2
Group 1 - OxNo: +1
Group 2 - OxNo: +2
Element - OxNo: 0
Flourine & Oxygen - OxNo: +2
Redox Reactions
Reduction and oxidation
Both occur but to different elements
Disproportionation Reaction
Both occur to the SAME element
Oxidation agent - gains electrons
Reduction agent - loses electrons
Groups 2 & 7
GROUP 2
Properties
High melting points
High boiling points
Low densities
Colourless compounds formed
Giant metallically bonded (See bonding section)
React by losing 2 electrons from their outer shell to the "sea of delocalised electrons"
GROUP 7
Halogens
Flourine
Chlorine
Bromine
Iodine
Astatine
Colours
Cl2(g)
Element - pale yellow
In H2O - pale yellow
In cyclohexane - yellow
Br2(l)
Element - orange
In H2O - orange
In cyclohexane - dark orange
I2(s)
Element - grey
In H2O - red/brown
In cyclohexane - purple
If the halogen is more reactive than the halogen in the compound, it will be displaced
Acids & Bases
Acids
HCl - Strong acid
Ethanoic - Weak acid
All contain H+
An acid is a PROTON DONOR
Bases
A base is a PROTON ACCEPTOR
Can be:
Metal oxides
Metal hydroxides
Soluble in water
Produce OH-
pH > 7
Metal carbonates
Ammonia
NH3 + H2O -> NH4OH
Neutralise acids
A SALT FORMS WHEN THE HYDROGEN ATOMS OF AN ACID ARE REPLACED BY METAL IONS OR AMMONIUM IONS
Bonding
Metallic
Atoms are ionised
+ Ions are in a fixed lattice position
Outer shell electrons become delocalised
Giant metallic bonding
Conducts electricity
High melting point
Covalent
Simple molecular
Strong covalent bonds - not broken
Weak IMFs
Low melting point
Low boiling point
Do not conduct electricity
Giant covalent molecular
Strong covalent bonds - broken
Found only in:
Carbon - Graphite
Carbon - Diamond
Silicon
High melting point
Graphite - conducts electricity
Diamond - does not conduct electricity
Ionic
Electrostatic attraction between oppositely charged ions
Giant lattice structure
Conduct electricity when molten or dissolved in water
Doesn't conduct when solid
High melting point
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