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7159181
AS Chemistry - OCR - F321
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Chem - Exam 1 revision
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AS Chemistry - OCR - F321
Electronic Structure, Periodic Table and Structure of the Atoms & Isotopes
Inside an atom
Neutron
Proton
Electron
Definitions
Annotations:
Must learn these!
Molecule - How elements come together to complete their outer shell
Ion - An atom with a charge (+/-)
Element - Found on the periodic table
Mixture - 2 or more substances together which haven't reacted
Compound - Same as a mixture but a reaction has taken place
Atom - The smallest part of an element that keeps its chemical properties
THE RELATIVE ISOTOPIC MASS IS THE MASS OF THE ISOTOPE COMPARED TO 1/12 OF THE MASS OF AN ATOM OF CARBON-12
THE FIRST IONISATION ENERGY IS THE ENERGY REQUIRED TO REMOVE ONE ELECTRON FROM EACH ATOM IN 1 MOLE OF GASEOUS ATOMS TO FORM 1 MOLE OF GASEOUS 1+ IONS
Rules:
Molecules = Non-metals
+ Ions = Metals
- Ions = Non-metals
Molecular ions = don't follow these rules
Annotations:
Must learn these
Isotopes
Same number of PROTONS & ELECTRONS
Different number of NEUTRONS
Arrangement of Electrons in an Atom
Atomic Orbitals
s
Annotations:
Only need this one and p
Spherical
p
Annotations:
Only need this one and s
Dum bell shaped
3 make a sub-shell
d
f
Each orbital can hold a max. of 2 electrons
Points That Affect Ionisation Energy
Nuclear Charge
Larger charge - more energy needed
Shielding
More shielding - less energy needed
Distance From the Nucleus
Further from the nucleus - less energy needed
Oxidation Numbers
OXIDATION IS LOSS (of electrons)
REDUCTION IS GAIN (of electrons)
Oxidation is the addition of oxygen
Oxidation is an increase in the oxidation number
CO2 - OxNo: +4 -2
Group 1 - OxNo: +1
Group 2 - OxNo: +2
Element - OxNo: 0
Flourine & Oxygen - OxNo: +2
Redox Reactions
Reduction and oxidation
Both occur but to different elements
Disproportionation Reaction
Both occur to the SAME element
Oxidation agent - gains electrons
Reduction agent - loses electrons
Groups 2 & 7
GROUP 2
Properties
High melting points
High boiling points
Low densities
Colourless compounds formed
Giant metallically bonded (See bonding section)
React by losing 2 electrons from their outer shell to the "sea of delocalised electrons"
GROUP 7
Halogens
Flourine
Chlorine
Bromine
Iodine
Astatine
Colours
Cl2(g)
Element - pale yellow
In H2O - pale yellow
In cyclohexane - yellow
Br2(l)
Element - orange
In H2O - orange
In cyclohexane - dark orange
I2(s)
Element - grey
In H2O - red/brown
In cyclohexane - purple
If the halogen is more reactive than the halogen in the compound, it will be displaced
Moles Calculations
Avogadro's Constant = 6.02 x 10^23
MASS OF A SUBSTANCE WHICH HAS THE SAME NUMBER OF PARTICLES AS IN 12g OF CARBON-12
Moles = mass(g) / molar mass
n = m/Mr
Moles
Ratio
Whatever
Empirical formula
Find the molar ratio
Divide by the smallest number
Molecular formula
Empirical formula mass
Number of units in a molecule
1dm^3 = 1000 cm^3
Volume (gas) = moles x 24
concentration = moles / volume
Volume (solution) = moles / concentration
Molar mass = mass / moles
No. of atoms = moles x (6.02 x 10^23)
Acids & Bases
Acids
HCl - Strong acid
Ethanoic - Weak acid
All contain H+
An acid is a PROTON DONOR
Bases
A base is a PROTON ACCEPTOR
Can be:
Metal oxides
Metal hydroxides
Soluble in water
Produce OH-
pH > 7
Metal carbonates
Ammonia
NH3 + H2O -> NH4OH
Neutralise acids
A SALT FORMS WHEN THE HYDROGEN ATOMS OF AN ACID ARE REPLACED BY METAL IONS OR AMMONIUM IONS
Bonding
Metallic
Atoms are ionised
+ Ions are in a fixed lattice position
Outer shell electrons become delocalised
Giant lattice structure
Conducts electricity
High melting point
Covalent
Simple molecular
Strong covalent bonds - not broken
Weak IMFs
Low melting point
Low boiling point
Do not conduct electricity
Giant covalent molecular
Strong covalent bonds - broken
Found only in:
Carbon - Graphite
Carbon - Diamond
Silicon
High melting point
Graphite - conducts electricity
Diamond - does not conduct electricity
Ionic
Electrostatic attraction between oppositely charged ions
Giant lattice structure
Conduct electricity when molten or dissolved in water
Doesn't conduct when solid
High melting point
IMFs
Van der Waals'
Induced dipoles
Weakest
Induced dipoles
Constantly breaking
Permanent dipole
Medium
Hydrogen
Only found when hydrogen is bonded with:
Oxygen
Nitrogen
Flourine
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