Transition Elements 2 - Stereoisomerism

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Zusammenfassung der Ressource

Frage Antworten
What are stereoisomers? molecules with same connectivity but different spatial arrangement
What type of stereoisomerism do complex ions exhibit? Cis-Trans Optical
What conditions are required for stereoisomerism in square planar structures? 4 co-ordinate bonds 2 different monodentate ligands
How do complex ions bend the rules of cis-trans stereoisomerism? In organic meant to have C=C Not necessary for complex ions
Arrangement of ligands in square planar structures Ligands are arranged in the same plane at the corners of a square with 90' bond angles
Arrangements of identical ligands in cis-isomerism of square planars Two identical groups are adjacent to each other 90' apart
Arrangement of identical ligands in trans- square planar Identical ligands are opposite each other 180' apart
Optical isomerism only occurs in what? What conditions must be met? octahedral complexes Must have 2 or more bidentate ligands
How does cis-platin work? Forms Pt complex in cell Binds to DNA Prevents DNA replication Triggers apoptosis
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